Element charge lookup

Hydrogen Charge: +1 or -1?

Hydrogen commonly forms H+ H- in introductory ionic compounds.

Hydrogen is +1 in almost every compound you meet in a first-year course: HCl, H2O, H2SO4. The exception is metal hydrides such as NaH and CaH2, where hydrogen sits on the metal side of the bond and carries a -1 charge as the hydride ion, H-.
ElementHydrogen
SymbolH
Atomic number1
Common ionic charge+1, -1
Common ionsH+, H-
Visual reference

Hydrogen element image and atomic model

Images are used as visual references; charge rules still depend on the compound.

Hydrogen element sample
Hydrogen sample imageUser:Jurii, CC BY 3.0 <https://creativecommons.org/licenses/by/3.0>, via Wikimedia Commons, source: https://images-of-elements.com/hydrogen.phpOriginal image source
Hydrogen Bohr model
Hydrogen Bohr modelAtomic model image from the open Periodic-Table-JSON dataset. It is a simplified electron-shell reference, not a scale drawing.Original Bohr model source

The electron count behind Hydrogen's charge

Hydrogen has a single 1s electron. Losing it gives the bare proton H+, which is what acids donate in solution. But hydrogen is also just one electron short of the filled 1s2 configuration of helium, so when it bonds to a strongly electropositive metal it gains an electron instead and becomes hydride.

The classic Hydrogen error

Students often write hydrogen as -1 in water because it is 'bonded to oxygen.' Direction matters: oxygen is more electronegative, so oxygen takes the electrons and hydrogen stays +1. Hydrogen is only -1 when its partner is a metal less electronegative than itself.

Worked example: H in a formula problem

Write the formula for calcium hydride.

Calcium is a Group 2 metal, so Ca2+. Hydride is H-. Two hydrides balance one calcium: CaH2.

H+ and H- in real compounds

HCl

Hydrogen chloride

H+ balances chloride ions.

H2O

Hydrogen oxide

Hydrogen can form oxides where total positive and negative charge balances.

Questions students ask about hydrogen

Is hydrogen ever neutral in a compound?

In elemental H2 the oxidation state is 0, but inside compounds hydrogen is assigned +1 (with nonmetals) or -1 (with metals). There is no common compound where it stays 0.

Why does the periodic table sometimes put hydrogen above lithium and above fluorine?

Because it behaves both ways: it forms +1 ions like the alkali metals and -1 ions like the halogens. Its placement is a compromise, not a rule about its charge.

What charge does hydrogen have in NaH?

-1. Sodium must be +1, and the compound is neutral, so hydrogen carries the negative charge. NaH is a classic hydride.

Where this data comes from

Charges and element facts on this page are checked against the primary references below. Found an error? Email hello@periodictablewithcharges.com — corrections ship in the next content update. See how this site is edited.

Neighbors of H on the table