Element charge lookup

What Is the Charge of Aluminum?

Aluminum commonly forms Al3+ in introductory ionic compounds.

Aluminum forms a 3+ ion, Al3+, in all of its common compounds: Al2O3 (the oxide skin that stops cans from corroding), AlCl3, and the alum in water treatment. No Roman numerals needed — aluminum has one setting.
ElementAluminum
SymbolAl
Atomic number13
Common ionic charge+3
Common ionsAl3+
Visual reference

Aluminum element image and atomic model

Images are used as visual references; charge rules still depend on the compound.

Aluminium element sample
Aluminum sample imageJurii, CC BY 3.0 <https://creativecommons.org/licenses/by/3.0>, via Wikimedia Commons, source: https://images-of-elements.com/aluminium.php Original image source
Aluminium Bohr model
Aluminum Bohr modelAtomic model image from the open Periodic-Table-JSON dataset. It is a simplified electron-shell reference, not a scale drawing.Original Bohr model source

How Aluminum's outer electrons decide its charge

Aluminum is [Ne]3s2 3p1. All three outer electrons go, exposing the neon core; a fourth would have to come out of that core, which is off the table energetically. Unlike true transition metals, aluminum has no d electrons to juggle, so there is no second common charge.

The Aluminum mistake worth a warning

Giving aluminum a Roman numeral — 'aluminum(III) oxide' — on naming exercises. Roman numerals are reserved for metals with multiple charges (iron, copper, lead). Aluminum is fixed at 3+, so it is just 'aluminum oxide.'

Worked example: Al in a formula problem

Write the formula for aluminum sulfate, used to clarify drinking water.

Al3+ and SO4 2-. Cross to the lowest common multiple of 6: two Al3+ (+6) and three sulfates (-6) give Al2(SO4)3.

Al3+ in real compounds

AlCl3

Aluminum chloride

Al3+ balances chloride ions.

Al2O3

Aluminum oxide

Aluminum can form oxides where total positive and negative charge balances.

Questions students ask about aluminum

Why is Al3+ so small, and why does it matter?

Radius just 54 pm — a lot of charge in a tiny package. That high charge density is why Al3+ grabs six water molecules in solution and why aluminum solutions are mildly acidic.

Can aluminum be 1+ like some textbooks' 'AlCl' suggests?

Al(I) species exist only at high temperature in the gas phase and disproportionate immediately at room temperature. For every school and lab purpose, aluminum is 3+.

What is the charge of aluminum in foil?

Zero — foil is elemental metal. The instant the surface meets air it forms a nanometers-thin Al2O3 layer (aluminum 3+ there), which seals and protects the neutral metal underneath.

Where this data comes from

Charges and element facts on this page are checked against the primary references below. Found an error? Email hello@periodictablewithcharges.com — corrections ship in the next content update. See how this site is edited.

Neighbors of Al on the table